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Please use this identifier to cite or link to this item: http://hdl.handle.net/10090/3791

Title: Analyzing the cation exchange capacity and soil organic matter in a Maryland Coastal Plain Ultisol after two prescribed burns
Authors: Prior, Chelsea Alexandra
Issue Date: 21-Jan-2008
Abstract: Grassland restoration projects are designed to restore native habitats on former agricultural land on the Mid-Atlantic Coastal Plain and other areas with the support of the Conservation Reserve Program (CRP) and the Conservation Reserve Enhancement Program (CREP). Land once farmed for 60 years in Queen Anne’s County, Maryland, was used for a grassland restoration project. The 92-ha of land was drilled-seeded with warm-season grasses, such as little bluestem, big bluestem and eastern gamagrass and sectioned off into 12 representative fields. The Ultisol soils on the Eastern Shore of Maryland are characterized by being low in nutrients, low in organic matter and moderately acidic. Prescribed burning was selected to help aid in maintaining the grassland restoration process. The burns increase productivity of grasses by allowing more available light and allow more nutrients to be released into the soil for plant uptake. Soil core samples, 10 cm in depth, were taken from 9 locations within a 13-ha field 1 day before, 11 days after and 1 year after a first prescribed burn, and 12 days after a third prescribed burn. Total soil organic matter (SOM) content was determined by loss-onignition method and total soil cation exchange capacity (CEC) was determined by the barium compulsive exchange method. Total SOM content increased from pre-burn values in samples taken 12 days after the third burn. These increases could have been due to the fact that a year after the first burn, total SOM content did not fall below pre-burn values, so a small build-up of ash is present after each burn. Total available CEC sites were determined via weight of the soil during the compulsive exchange procedure and by atomic absorption spectrophotometry. The two methods gave different results for CEC, suggesting that the weight method is not as accurate. Overall CEC data shows a decrease v both a year after the first burn and 12 days after the third burn as compared to pre-burn conditions in all three layers. In the bottom layer, the CEC following the third burn was overall lower than a year after the first burn. These decreases after the third burn could have been because of the functional groups believed to exist on the ash were still protonated, which prohibited any cations to bind to those sites. This was likely affected by the decreases in soil pH values found at these times. After the third burn, the relationships between CEC, SOM and extractable cations Ca2+, Mg2+ and K+ were still correlated, although the relationships had changed. Results have shown that annual burns provide increase production in the grassland restoration projects.
Description: Submitted in partial fulfillment of the requirements for the degree of Bachelor of Science. May 2007 Thesis advisor: Leslie A. Sherman, Ph.D.
URI: http://hdl.handle.net/10090/3791
Appears in Collections:Washington College Chemistry Senior Capstone Experience

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